In this paper,measurements of rubies impregnated with organic-inorganic substance were carried out by microconfocal Raman spectrometer (785nm),XRF and infrared spectrometer.Based on analyses afterwards,it was shown that Raman shifts near at 1353cm-1 with 500cm-1 FWHM is attributed to lead glass,which was employed to cover interior cracks of ruby;While Raman shifts near at 2331,2874 and 3285cm-1 and infrared absorption bands near at 2927 and 2856cm-1,which are attributed to organic substance,might be being in Raman and IR spectra of rubies impregnated with organic substance.