甲烷中红外7.16μm吸收光谱参数测量
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

国家重点研发项目(No.2019YFB2006002);华能集团总部科技项目基础能源科技研究专项(一)(No.HNKJ-H50)资助。


Measurement of CH4 spectroscopic parameters at7.16μmusing QCL
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    介绍了一套高精度气体吸收光谱测量系统,并采用716μm的量子级联激光器(QCL)测量了甲烷(CH4)气体在该波长附近不同压力(5~30 kPa)和温度(290~1050K)范围的光谱参数。同时,本文不仅测量了纯甲烷环境下的分子自身光谱参数,还测量了其在Ar,N2和He三种不同相对分子质量的背景气下的各类谱线参数。实验发现,本文测量的甲烷谱线在不同环境下的碰撞展宽系数由大到小分别是:自身>N2>Ar>He,四种环境下测量谱线的压力频移系数均为负数,及谱线压力频移与压力呈负相关,其绝对值由大到小排列分别为:自身>N2>Ar>He,与碰撞展宽系数变化规律相同。本文对所有测量的谱线参数均计算了各自的不确定度且定量分析了各类不确定度的来源。

    Abstract:

    In this paper,a high precision gas absorption spectroscopy measurement system is introduced and a 7.16μmquantum cascade laser(QCL)is used to measure the spectral parameters of methane(CH4)gas at different pressure(5~30 kPa)and temperature(290~1050K)ranges around this wavelength.The spectral parameters of the molecule themselves are measured not only in the pure methane environment,but also in the background gases of Ar,N2 and He with different relative molecular masses.The experimental results show that the relative magnitudes of the CH4 collisional broadening coefficients of the methane spectral lines measured in different environments are from large to small:self>N2>Ar>He.The measured pressure shift coefficients of the spectral lines measured in the four environments are all negative,and the pressure frequency shift of the spectral lines is negatively correlated with the pressure,and their absolute values are from large to small:self>N2>Ar>He,which are the same as the change of the collisional broadening coefficients.The respective uncertainties are calculated for all measured spectral parameters and the sources of the various uncertainties are quantified.

    参考文献
    相似文献
    引证文献
引用本文

沈佳园,李济东,陈钻,刘翔,何国军,彭志敏.甲烷中红外7.16μm吸收光谱参数测量[J].激光与红外,2022,52(9):1306~1313
SHEN Jia-yuan, LI Ji-dong, CHEN Zuan, LIU Xiang, HE Guo-jun, PENG Zhi-min. Measurement of CH4 spectroscopic parameters at7.16μmusing QCL[J]. LASER & INFRARED,2022,52(9):1306~1313

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:
  • 最后修改日期:2021-10-17
  • 录用日期:
  • 在线发布日期: 2022-09-23
  • 出版日期: